{"id":14363,"date":"2019-08-12T23:58:20","date_gmt":"2019-08-12T15:58:20","guid":{"rendered":"https:\/\/blog.kohan.com.tw\/?p=14363"},"modified":"2021-03-31T13:41:49","modified_gmt":"2021-03-31T05:41:49","slug":"%e4%bb%a5mars-6%e5%af%86%e9%96%89%e5%bc%8f%e5%be%ae%e6%b3%a2%e6%b6%88%e5%8c%96%e5%99%a8%e9%80%b2%e8%a1%8c%e9%9b%bb%e5%ad%90%e6%9d%90%e6%96%99%e7%b5%84%e4%bb%b6%e7%9a%84%e5%85%ad%e5%83%b9%e9%89%bb","status":"publish","type":"post","link":"https:\/\/blog.kohan.com.tw\/%e5%85%83%e7%b4%a0%e5%88%86%e6%9e%90\/%e4%bb%a5mars-6%e5%af%86%e9%96%89%e5%bc%8f%e5%be%ae%e6%b3%a2%e6%b6%88%e5%8c%96%e5%99%a8%e9%80%b2%e8%a1%8c%e9%9b%bb%e5%ad%90%e6%9d%90%e6%96%99%e7%b5%84%e4%bb%b6%e7%9a%84%e5%85%ad%e5%83%b9%e9%89%bb\/","title":{"rendered":"\u4f9d\u5faaIEC 62321-7-2:2017\u6aa2\u6e2c\u65b9\u6cd5 \u2014 \u4ee5MARS 6\u5bc6\u9589\u5f0f\u5fae\u6ce2\u6d88\u5316\u5668\u9032\u884c\u96fb\u5b50\u6750\u6599\u7d44\u4ef6\u7684\u516d\u50f9\u927b\u5206\u6790"},"content":{"rendered":"

\u6b50\u76df\u65bc 2002 \u5e74\u767c\u4f48\u96fb\u6a5f\u96fb\u5b50\u8a2d\u5099\u4e2d\u6709\u5bb3\u7269\u8cea\u9650\u5236\u6cd5\u898f\uff08Restriction of Hazardous Substances Directive 2002\/95\/EC\uff0cRoHS\uff09\uff0c\u800c\u570b\u969b\u96fb\u5de5\u5354\u6703\uff08IEC\uff09\u516c\u544a\u76f8\u5c0d\u61c9\u7684\u516d\u50f9\u927b\u6aa2\u6e2c\u65b9\u6cd5 IEC 62311:2008\uff0c\u5176\u90e8\u4efd\u5167\u5bb9\u5df2\u88ab\u65b0\u7684\u6aa2\u6e2c\u65b9\u6cd5 IEC 62321-7-2:2017 \u6240\u53d6\u4ee3\u3002\u672c\u7bc7\u6587\u7ae0\u5c07\u4ecb\u7d39\u5982\u4f55\u7528\u5bc6\u9589\u5f0f\u5fae\u6ce2\u6d88\u5316\u5668<\/a>\u9032\u884c\u516d\u927b\u5206\u6790\u7684\u6a23\u54c1\u524d\u8655\u7406\uff0c\u4e26\u8f15\u9b06\u7b26\u5408 IEC 62321-7-2:2017 \u6aa2\u6e2c\u65b9\u6cd5\u3002<\/p>\n

IEC 62321-7-2:2017 \u6aa2\u6e2c\u65b9\u6cd5<\/h3>\n

\u96a8\u8457\u96fb\u5b50\u8a2d\u5099\u7d44\u4ef6\u7684\u5e02\u5834\u8d8a\u4f86\u8d8a\u5927\uff0c\u4eba\u5011\u4e5f\u8d8a\u4f86\u8d8a\u95dc\u6ce8\u96fb\u5b50\u8a2d\u5099\u7d44\u4ef6\u5c0d\u65bc\u74b0\u5883\u7684\u5f71\u97ff\u3002\u7531\u65bc\u516d\u50f9\u927b\u53ef\u80fd\u6703\u6c61\u67d3\u571f\u58e4\u8207\u6c34\uff0c\u6216\u85c9\u7531\u76ae\u819a\u63a5\u89f8\u800c\u651d\u5165\u4eba\u9ad4\u5167\uff0c\u5291\u91cf\u9ad8\u6642\u6703\u5c0d\u4eba\u9ad4\u7522\u751f\u5371\u5bb3\uff0c\u76ee\u524d\u591a\u6578\u570b\u5bb6\u90fd\u63a1\u7528\u4e86\u6709\u5bb3\u7269\u8cea\u9650\u5236\u6cd5\u898f\uff08RoHS\uff09\u4f86\u9650\u5236\u516d\u50f9\u927b\u7684\u4f7f\u7528\uff0c\u8fd1\u671f\u570b\u969b\u96fb\u5de5\u5354\u6703\uff08IEC\uff09\u516c\u544a\u4e86\u65b0\u7684\u6aa2\u6e2c\u65b9\u6cd5 IEC 62321-7-2:2017 \u4f86\u5206\u6790\u805a\u5408\u7269\u8207\u96fb\u5b50\u96f6\u4ef6\u7522\u54c1\u4e2d\u7684\u516d\u50f9\u927b\u6fc3\u5ea6\uff0c\u6b64\u65b0\u65b9\u6cd5\u53d6\u4ee3\u4e86 IEC 62311:2008 \u4e2d\u7684\u90e8\u5206\u5167\u5bb9\u3002<\/p>\n

IEC 62321-7-2:2017 \u662f\u4f7f\u7528\u7d2b\u5916\u5149-\u53ef\u898b\u5149\u5206\u5149\u5149\u8b5c\u5100\uff08UV-Vis Spectrophotometer\uff09\u4f86\u6e2c\u5b9a\u805a\u5408\u7269\u8207\u96fb\u5b50\u6750\u6599\u4e2d\u7684\u516d\u50f9\u927b\u6fc3\u5ea6\u3002\u91dd\u5c0d\u7121\u6cd5\u4ee5\u8d85\u97f3\u6ce2\u9707\u76ea\u6eb6\u89e3\u6216\u672a\u77e5\u6210\u5206\u7684\u805a\u5408\u7269\u8207\u96fb\u5b50\u6750\u6599\uff0c\u5fc5\u9808\u4ee5\u5fae\u6ce2\u6d88\u5316\u4f86\u9032\u884c\u6a23\u54c1\u524d\u8655\u7406\uff0c\u4ee5\u4e0b\u5c07\u8aaa\u660e\u5982\u4f55\u4f7f\u7528 MARS 6 \u5fae\u6ce2\u6d88\u5316\u7cfb\u7d71<\/a>\u5efa\u7acb\u6b63\u78ba\u7684\u5fae\u6ce2\u6d88\u5316\u7a0b\u5e8f\u4f86\u7b26\u5408\u8a72\u65b9\u6cd5\uff0c\u8b93\u4f7f\u7528\u8005\u5011\u66f4\u5bb9\u6613\u9075\u5faa\u3002<\/section>\n
\n

\u516d\u50f9\u927b\u5206\u6790\u5be6\u9a57\u64cd\u4f5c\u6d41\u7a0b<\/h3>\n

\u5fae\u6ce2\u6d88\u5316\u7cfb\u7d71<\/h4>\n

\u4f7f\u7528 CEM MARS6 \u5bc6\u9589\u5f0f\u5fae\u6ce2\u6d88\u5316\u5668<\/a>\u8207 MARSXpress \u5bc6\u9589\u5f0f\u9ad8\u7522\u91cf\u53cd\u61c9\u74f6\u7d44<\/a>\u9032\u884c\u516d\u50f9\u927b\u5206\u6790\u7684\u6a23\u54c1\u524d\u8655\u7406\u3002<\/p>\n<\/section>\n<\/div>

<\/span><\/div><\/div>

 <\/p>\n

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\n
\n
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(\u5de6\u5716) CEM MARS 6 \u5bc6\u9589\u5f0f\u5fae\u6ce2\u6d88\u5316\u5668\uff1b(\u53f3\u5716) MARS Xpress \u5bc6\u9589\u5f0f\u9ad8\u7522\u91cf\u53cd\u61c9\u74f6\u7d44<\/h6>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/section>\n

 <\/p><\/h6><\/div>

<\/div><\/div><\/div><\/div>

\u8a66\u5291\u88fd\u5099<\/h4>\n

\u6a23\u54c1\u88fd\u5099\u524d\u9700\u5b8c\u6210\u8a66\u5291\u914d\u88fd\uff0c\u6240\u6709\u8a66\u5291\u5fc5\u9808\u70ba\u8a66\u85e5\u7b49\u7d1a\u4ee5\u4e0a\u3002<\/p>\n

    \n
  • \u6d88\u5316\u6db2\uff08Digestion Solution\uff09\uff1a \u5c07 20 g \u7684\u6c2b\u6c27\u5316\u9209\uff08NaOH\uff09\u8207 30 g \u7684\u78b3\u9178\u9209\uff08Na2CO3\uff09\u6eb6\u89e3\u65bc\u4e00\u516c\u5347\u7684\u5b9a\u91cf\u74f6\u4e2d\uff0c\u4e26\u7528\u53bb\u96e2\u5b50\u6c34\u5b9a\u91cf\u5230\u523b\u7dda\uff0c\u6b64\u6d88\u5316\u6db2\u5fc5\u9808\u6bcf\u6708\u65b0\u9bae\u914d\u88fd\u4e26\u5b58\u653e\u65bc 20 \uff5e 25 \u00b0C \u7684\u74b0\u5883\u4e2d\uff0c\u4f7f\u7528\u524d\u9700\u8981\u6e2c\u8a66 pH \u503c\uff0c\u82e5 pH \u503c\u4f4e\u65bc 11.5 \u5247\u9700\u91cd\u65b0\u914d\u7f6e\u3002<\/li>\n
  • \u78f7\u9178\u9e7d\u7de9\u885d\u5291\uff08Phosphate Buffer\uff09\uff1a \u65bc\u4e00\u516c\u5347\u7684\u5b9a\u91cf\u74f6\u4e2d\u52a0\u5165 87.09 g \u7684\u78f7\u9178\u6c2b\u4e8c\u9240\uff08K 2 HPO4\uff09\u8207 68.04 g \u7684\u78f7\u9178\u4e8c\u6c2b\u9240\uff08KH2PO4\uff09\u52a0\u5165 700 mL \u7684\u53bb\u96e2\u5b50\u6c34\u5747\u52fb\u6eb6\u89e3\uff0c\u518d\u4f7f\u7528\u53bb\u96e2\u5b50\u6c34\u5c07\u5176\u5b9a\u91cf\u5230\u523b\u7dda\u3002<\/li>\n
  • 35 % \u785d\u9178\uff08Nitric Acid at 35 %\uff09\uff1a \u5c07 50 mL \u7684\u785d\u9178\u6eb6\u6db2\u4f7f\u7528\u53bb\u96e2\u5b50\u6c34\u7a00\u91cb\u5230 100 mL\uff0c\u4e26\u5b58\u653e\u65bc\u5ba4\u6eab 20 \u00b0C \u7684\u74b0\u5883\u4e2d\u3002<\/li>\n
  • \u4e8c\u82ef\u80fa\u57fa\u8132\u6eb6\u6db2\uff08Diphenylcarbazide Solution\uff09\uff1a \u5c07 250 mg \u7684\u4e8c\u82ef\u80fa\u57fa\u8132\u6eb6\u89e3\u65bc 50 mL \u4e19\u916e\u4e2d\uff0c\u4e26\u5b58\u653e\u65bc\u8910\u8272\u74f6\u4e2d\uff0c\u4f7f\u7528\u524d\u6aa2\u67e5\u6eb6\u6db2\u662f\u5426\u8b8a\u8272\uff0c\u82e5\u6eb6\u6db2\u8b8a\u8272\u5247\u9700\u8981\u68c4\u7f6e\u91cd\u914d\u3002<\/li>\n
  • 10 %\u786b\u9178\uff08Sulfuric Acid at 10 %\uff09\uff1a \u5c07 10 mL \u7684\u84b8\u993e\u8a66\u5291\u7b49\u7d1a\u6216\u5149\u8b5c\u7b49\u7d1a\u7684\u786b\u9178\u4ee5\u53bb\u96e2\u5b50\u6c34\u7a00\u91cb\u5230 100 mL\uff0c\u4e26\u5b58\u653e\u7f6e\u5b9a\u91cf\u74f6\u4e2d\u3002<\/li>\n
  • \u5176\u4ed6\u8a66\u5291\u9700\u6c42\uff1a \u5206\u6790\u7b49\u7d1a\u7532\u82ef\uff08Toluene\uff09\u3002 \u5206\u6790\u7b49\u7d1a\u7121\u6c34\u6c2f\u5316\u9382\uff08MgCl2\uff09\u3002<\/li>\n<\/ul>\n

    \u5fae\u6ce2\u6d88\u5316\u7a0b\u5e8f<\/h4>\n
      \n
    1. \u79e4\u7d04 0.15 g \u7684\u6a23\u54c1\uff0c\u653e\u7f6e\u65bc\u6d88\u5316\u7ba1\u4e2d\uff0c\u4e26\u653e\u5165\u652a\u62cc\u78c1\u77f3\u3002<\/li>\n
    2. \u52a0\u5165 10 mL \u7684\u6d88\u5316\u6db2\u3002<\/li>\n
    3. \u52a0\u5165 5 mL \u7684\u7532\u82ef\u6eb6\u6db2\u3002<\/li>\n
    4. \u52a0\u5165 400 mg \u7684\u7121\u6c34\u6c2f\u5316\u9382\u3002<\/li>\n
    5. \u52a0\u5165 0.5 mL \u7684\u78f7\u9178\u9e7d\u7de9\u885d\u5291\u3002<\/li>\n
    6. \u4f7f\u7528\u9396\u74f6\u5de5\u5177\u9069\u7576\u5730\u9396\u74f6\u5f8c\uff0c\u5c07\u6d88\u5316\u74f6\u7d44\u5e73\u5747\u653e\u7f6e\u5165\u8f49\u76e4\u4e2d\u4e26\u653e\u5165\u5fae\u6ce2\u7210\u8154\uff0c\u5fae\u6ce2\u6d88\u5316\u689d\u4ef6\u8a73\u898b\u4e0b\u8868 1\u3002<\/li>\n<\/ol>\n
      \n
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      \n
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      \u8868 1\uff1a\u516d\u50f9\u927b\u5206\u6790\u524d\u8655\u7406\u5fae\u6ce2\u6d88\u5316\u689d\u4ef6<\/h6>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/section><\/div>\n \n \n \n \n \n \n <\/colgroup>\n \n\n \n\n \n \n
      \u968e\u6bb5\uff08Stage\uff09<\/th>\u5347\u6eab\u6642\u9593\uff08Ramp\uff09<\/th>\u6eab\u5ea6 \uff08Temp\u00b0C\uff09<\/th>\u6301\u6eab\u6642\u9593\uff08Hold\uff09<\/th><\/tr>\n<\/thead>\n
      1<\/td>15 \u5206\u9418<\/td>155 \u00b0C<\/td>60 \u5206\u9418<\/td> <\/tr>\n
      2<\/td>1 \u79d2<\/td>155 \u00b0C<\/td>30 \u5206\u9418<\/td> <\/tr>\n <\/tbody>\n <\/table>\n