{"id":16627,"date":"2023-07-07T16:29:23","date_gmt":"2023-07-07T08:29:23","guid":{"rendered":"https:\/\/blog.kohan.com.tw\/?p=16627"},"modified":"2023-09-13T15:45:42","modified_gmt":"2023-09-13T07:45:42","slug":"%e7%a9%bf%e9%80%8f%e5%bc%8f-atr-%e5%8f%8d%e5%b0%84%e5%bc%8fftir%e6%8a%80%e8%a1%93%e6%af%94%e8%bc%83%e8%88%87ftir%e9%a1%af%e5%be%ae%e6%88%90%e5%83%8f%e5%88%86%e4%ba%ab","status":"publish","type":"post","link":"https:\/\/blog.kohan.com.tw\/%e5%88%86%e6%9e%90%e8%88%87%e9%91%91%e5%ae%9a\/%e7%a9%bf%e9%80%8f%e5%bc%8f-atr-%e5%8f%8d%e5%b0%84%e5%bc%8fftir%e6%8a%80%e8%a1%93%e6%af%94%e8%bc%83%e8%88%87ftir%e9%a1%af%e5%be%ae%e6%88%90%e5%83%8f%e5%88%86%e4%ba%ab\/","title":{"rendered":"\u7a7f\u900f\u5f0f\/ATR\/\u53cd\u5c04\u5f0fFTIR\u6280\u8853\u6bd4\u8f03\u8207FTIR\u986f\u5fae\u6210\u50cf\u5206\u4eab"},"content":{"rendered":"
\u8ac7\u904eFTIR\u539f\u7406<\/a>\u5f8c\uff0c\u4eca\u5929\u4f86\u8ac7\u8ac7FTIR\u7684\u91cf\u6e2c\u6280\u8853\u3002FTIR\u6307\u7684\u662f\u4ee5\u5085\u7acb\u8449\u8f49\u63db\u6cd5\u9032\u884c\u6578\u64da\u6536\u96c6\u904b\u7b97\u7684\u7d05\u5916\u7dda\u5149\u8b5c\u5100<\/a>\uff0c\u5982\u679c\u8981\u5728\u66f4\u9032\u4e00\u6b65\u7d30\u5206\u4e0b\u53bb\uff0c\u5176\u5be6FTIR\u9084\u53ef\u4ee5\u5206\u70ba\u4e09\u7a2e\u4e0d\u540c\u7684\u91cf\u6e2c\u65b9\u5f0f\uff1a\u7a7f\u900f\u5f0f\u3001\u53cd\u5c04\u5f0f\u8207ATR(\u8870\u6e1b\u5168\u53cd\u5c04)\uff0c\u9019\u4e9b\u6280\u8853\u90fd\u57fa\u65bcFTIR\u57fa\u672c\u539f\u7406\u53bb\u7372\u53d6\u6578\u64da\uff0c\u4f46\u7d05\u5916\u7dda\u5149\u8b5c\u7522\u751f\u4e26\u4e0d\u76f8\u540c\uff0c\u56e0\u6b64\u9069\u7528\u7684\u6a23\u54c1\u4e5f\u7565\u70ba\u4e0d\u540c\uff0c\u672c\u6b21\u5206\u4eab\u7684\u5167\u5bb9\u6703\u5148\u5f9e\u9019\u4e09\u7a2e\u6280\u8853\u8aaa\u8d77\uff0c\u8b93\u5404\u4f4d\u53ef\u4ee5\u66f4\u52a0\u77ad\u89e3FTIR\u5149\u8b5c\u5100\u7684\u7d30\u7bc0\uff0c\u4e86\u89e3\u958b\u5982\u4f55\u9078\u64c7\u9069\u5408\u60a8\u6a23\u54c1\u7684\u91cf\u6e2c\u6280\u8853\uff0c\u53e6\u5916\u518d\u52a0\u78bc\u5206\u4eab\u8fd1\u5e74\u4f86\u66f4\u52a0\u65b0\u7a4e\u7684\u61c9\u7528\uff1a\u986f\u5faeFTIR\u8207FTIR\u6210\u50cf\u6280\u8853\u3002<\/p>\n<\/div> \u7a7f\u900f\u5f0f\u6280\u8853\u662f\u6700\u539f\u59cb\u7684\u7d05\u5916\u7dda\u91cf\u6e2c\u6280\u8853\u3002\u7576\u7d05\u5916\u7dda\u7a7f\u900f\u6a23\u54c1\uff0c\u6a23\u54c1\u6703\u5438\u6536\u90e8\u5206\u7d05\u5916\u7dda\uff0c\u5269\u9918\u7684\u7d05\u5916\u7dda\u7a7f\u904e\u6a23\u54c1\u4e26\u88ab\u63a2\u6e2c\u5668\u63a5\u6536\uff0c\u4e26\u85c9\u7531\u8edf\u9ad4\u8f49\u63db\u70ba\u7a7f\u900f\u5f0f\u7d05\u5916\u7dda\u5149\u8b5c\uff0c\u904b\u4f5c\u908f\u8f2f\u5341\u5206\u7c21\u55ae\u6613\u61c2\u3002<\/p>\n<\/div> \u96d6\u7136\u904b\u4f5c\u908f\u8f2f\u7c21\u55ae\uff0c\u4f46\u5be6\u969b\u64cd\u4f5c\u8d77\u4f86\u672a\u5fc5\u5982\u6b64\u65b9\u4fbf\u3002\u8209\u4f8b\uff0c\u82e5\u6a23\u54c1\u56e0\u70ba\u592a\u539a\uff0c\u7a7f\u904e\u6a23\u54c1\u5f8c\u5269\u4e0b\u7684\u7d05\u5916\u7dda\u6703\u904e\u5c11\uff0c\u6703\u8b93\u5716\u8b5c\u54c1\u8cea\u8b8a\u5dee\uff1b\u6216\u662f\u6a23\u54c1\u70ba\u7c89\u672b\u72c0\uff0c\u7d05\u5916\u7dda\u53ef\u80fd\u7121\u6cd5\u7a69\u5b9a\u7a7f\u904e\u6a23\u54c1\uff0c\u5f71\u97ff\u5be6\u9a57\u518d\u73fe\u6027\u3002\u70ba\u4e86\u907f\u514d\u9019\u4e9b\u6e2c\u91cf\u554f\u984c\uff0c\u6a23\u54c1\u9700\u8981\u8655\u7406\u904e\u624d\u80fd\u5206\u6790\uff0c\u50cf\u662f\u5207\u8584\u3001\u6253\u9320\u6216\u7a00\u91cb\u7b49\uff0c\u6839\u64da\u6a23\u54c1\u578b\u614b\u4e0d\u540c\uff0c\u8655\u7406\u65b9\u5f0f\u4e5f\u6703\u4e0d\u540c\uff0c\u4ee5\u4e0b\u70ba\u5e7e\u7a2e\u5e38\u898b\u7684\u6a23\u54c1\u578b\u614b\u8207\u8655\u7406\u65b9\u5f0f\uff1a<\/p>\n \u7c21\u55ae\u4f86\u8aaa\uff0c\u7a7f\u900f\u5f0fFTIR\u5e38\u9700\u8981\u4e8b\u5148\u8655\u7406\u6a23\u54c1\uff0c\u800c\u9019\u4e9b\u8655\u7406\u65b9\u5f0f\u5f80\u5f80\u662f\u7834\u58de\u6027\u7684\uff0c\u6240\u4ee5\u5728\u73fe\u4eca\u7684\u61c9\u7528\u4e0a\uff0c\u7a7f\u900f\u5f0fFTIR\u50c5\u7528\u65bc\u7279\u5b9a\u7684\u9818\u57df\uff0c\u4f8b\u5982\u6aa2\u67e5\u805a\u5408\u7269\u8584\u819c\u3001\u86cb\u767d\u8cea\u6216\u662f\u6c34\u4e2d\u7684\u6cb9\u5206\u7b49\uff0c\u4e5f\u88ab\u5ee3\u6cdb\u61c9\u7528\u5728\u6cd5\u91ab\u9818\u57df\uff0c\u7528\u4f86\u5206\u6790\u7d44\u7e54\u6a23\u54c1\u6216\u5851\u81a0\u5fae\u7c92\u3002<\/p>\n ATR\u5168\u540d\u70baAttenuated Total Reflection\uff0c\u4e5f\u7a31\u70ba\u8870\u6e1b\u5f0f\u5168\u53cd\u5c04\uff0c\u7531\u65bc\u4e0d\u9700\u8981\u6a23\u54c1\u524d\u8655\u7406\uff0c\u5df2\u7d93\u6210\u70ba\u73fe\u5728FTIR\u6e2c\u91cf\u6280\u8853\u7684\u4e3b\u6d41\u3002\u5728\u9032\u884cATR\u6aa2\u6e2c\u6642\uff0c\u6a23\u54c1\u88ab\u7f6e\u65bc\u6676\u9ad4\u9802\u7aef(\u901a\u5e38\u7531\u947d\u77f3\u3001\u937a\u6216\u7852\u5316\u92c5\u88fd\u6210)\uff0c\u7576\u7d05\u5916\u7dda\u7a7f\u904e\u6676\u9ad4\u4e26\u63a5\u89f8\u5230\u6a23\u54c1\u6642\uff0c\u4e00\u90e8\u5206\u7684\u7d05\u5916\u7dda\u88ab\u6a23\u54c1\u5438\u6536\uff0c\u5269\u4e0b\u7684\u7d05\u5916\u7dda\u88ab\u53cd\u5c04\u4e26\u518d\u6b21\u901a\u904e\u6676\u9ad4\uff0c\u6700\u5f8c\u62b5\u9054\u5230\u63a2\u6e2c\u5668\u4e0a\u3002<\/p>\n<\/div> \u5728\u9019\u7a2e\u6280\u8853\u4e2d\uff0c\u53ea\u6709\u4e00\u5c0f\u90e8\u5206\u7684\u7d05\u5916\u7dda\u6703\u8f15\u5fae\u7a7f\u900f\u904e\u6a23\u54c1\u4e26\u8fc5\u901f\u8870\u6e1b(\u7a31\u70baevanescent field\u6216evanescent wave)\uff0c\u6240\u4ee5\u7d05\u5916\u7dda\u8207\u6a23\u54c1\u6703\u6709\u5e7e\u5fae\u7c73\u7684\u4ea4\u4e92\u4f5c\u7528\uff0c\u4e0d\u50cf\u7a7f\u900f\u5f0f\u7d05\u5916\u7dda\u90a3\u6a23\u5b8c\u5168\u7a7f\u904e\u6a23\u54c1\uff0c\u6240\u4ee5ATR\u9032\u884c\u7d05\u5916\u7dda\u5149\u8b5c\u5206\u6790\u6642\u5e7e\u4e4e\u4e0d\u9700\u8981\u6a23\u54c1\u524d\u8655\u7406\uff0c\u4f7f\u9019\u7a2e\u5206\u6790\u6280\u8853\u57f7\u884c\u8d77\u4f86\u975e\u5e38\u7c21\u55ae\uff0c\u4e0d\u8ad6\u662f\u6db2\u9ad4\u3001\u7c89\u9ad4\u3001\u7cca\u72c0\u7269\u7b49\uff0c\u5e7e\u4e4e\u6240\u6709\u985e\u578b\u7684\u6a23\u54c1\u90fd\u53ef\u4ee5\u4f7f\u7528\uff0c\u800c\u4e14ATR\u5728\u5be6\u9a57\u5f8c\u5f88\u5bb9\u6613\u6e05\u6f54\uff0c\u53ea\u8981\u8edf\u5e03\u8ddf\u4e00\u9ede\u9152\u7cbe\u5c31\u5920\u4e86\u3002<\/p>\n<\/div> ATR\u975e\u5e38\u842c\u7528\uff0c\u4f46\u5fc5\u9808\u6839\u64da\u6a23\u54c1\u7684\u7279\u6027\u9078\u64c7\u9069\u7576\u6676\u9ad4\uff0c\u5e38\u7528\u7684\u6676\u9ad4\u6709\u4e09\u7a2e\uff1a\u947d\u77f3\u3001\u937a\u4ee5\u53ca\u7852\u5316\u92c5\u3002<\/p>\n<\/div> \u53e6\u4e00\u7a2e\u53ef\u4ee5\u8003\u616e\u4f7f\u7528\u7684\u6676\u9ad4\u914d\u4ef6\u662f\u591a\u91cd\u53cd\u5c04\u914d\u4ef6\uff0c\u7531\u7852\u5316\u92c5\u88fd\u6210\u7684\u9577\u65b9\u5f62ATR\u6676\u9ad4\uff0c\u53ef\u4ee5\u8b93\u7d05\u5916\u7dda\u9032\u884c\u591a\u6b21\u53cd\u5c04\uff0c\u9019\u8868\u793a\u53ef\u4ee5\u589e\u52a0\u6a23\u54c1\u5438\u6536\u7684\u7d05\u5916\u7dda\u91cf\uff0c\u5c0d\u65bc\u7d05\u5916\u7dda\u5438\u6536\u80fd\u529b\u4f4e\u6216\u6fc3\u5ea6\u8f03\u4f4e\u7684\u6a23\u54c1\u4f86\u8aaa\uff0c\u6b64\u914d\u4ef6\u53ef\u63d0\u4f9b\u66f4\u9ad8\u54c1\u8cea\u7684\u7d05\u5916\u7dda\u5716\u8b5c\u3002<\/p>\n<\/div> \u82e5\u63a2\u6e2c\u5668\u63a5\u6536\u7684\u662f\u88ab\u6a23\u54c1\u53cd\u5c04(reflection)\u7684\u7d05\u5916\u7dda\uff0c\u5f97\u5230\u7684\u5716\u8b5c\u5247\u662f\u53cd\u5c04\u5f0f\u7d05\u5916\u7dda\u5149\u8b5c\u3002\u7531\u65bc\u9019\u7a2e\u6e2c\u91cf\u65b9\u5f0f\u50c5\u6aa2\u6e2c\u5f9e\u6a23\u54c1\u8868\u9762\u53cd\u5c04\u7684\u7d05\u5916\u7dda\uff0c\u6240\u4ee5\u80fd\u7528\u65bc\u5206\u6790\u7d05\u5916\u7dda\u7121\u6cd5\u7a7f\u900f\uff0c\u6216\u662f\u7121\u6cd5\u4f7f\u7528ATR\u6280\u8853\u5206\u6790\u7684\u56fa\u9ad4\u6a23\u54c1\u3002<\/p>\n<\/div> \u6839\u64da\u7d05\u5916\u7dda\u8207\u6a23\u54c1\u53cd\u5c04\u7684\u5f62\u5f0f\uff0c\u53cd\u5c04\u5f0f\u7d05\u5916\u7dda\u5149\u8b5c\u5206\u70ba\u4e09\u7a2e\u985e\u578b\uff1a<\/p>\n<\/div> \u53c8\u88ab\u7a31\u70ba\u300ctransflectance\u300d\uff0c\u904b\u4f5c\u65b9\u5f0f\u8207\u7a7f\u900f\u5f0f\u7d05\u5916\u7dda\u5149\u8b5c\u5f88\u76f8\u4f3c\uff0c\u4f46\u6a23\u54c1\u53ea\u6703\u6709\u8584\u8584\u7684\u4e00\u5c64\uff0c\u5e95\u4e0b\u5fc5\u9808\u653e\u6709\u5177\u53cd\u5c04\u6027\u7684\u57fa\u8cea(\u4f8b\u5982\u91d1\u5c6c)\uff0c\u8b93\u7d05\u5916\u7dda\u5f97\u4ee5\u53cd\u5c04\uff0c\u9019\u7a2e\u5206\u6790\u65b9\u5f0f\u5e38\u7528\u65bc\u5176\u4ed6\u5149\u8b5c\u6280\u8853\u96e3\u4ee5\u5206\u6790\u7684\u6a23\u54c1\uff0c\u50cf\u662f\u5857\u5c64\u6216\u7d44\u7e54\u7b49\uff0c\u56e0\u6b64\u5ee3\u6cdb\u7528\u65bc\u6750\u6599\u79d1\u5b78\u3001\u8868\u9762\u79d1\u5b78\u548c\u751f\u7269\u5316\u5b78\u7b49\u9818\u57df\u3002<\/p>\n \u6a23\u54c1\u672c\u8eab\u5fc5\u9808\u662f\u5149\u6ed1\u7684\uff0c\u8b93\u7d05\u5916\u7dda\u53ef\u4ee5\u76f4\u63a5\u53cd\u5c04\uff0c\u4ee5\u907f\u514d\u51fa\u73fe\u6563\u5c04\u800c\u5f71\u97ff\u6578\u64da\uff0c\u9019\u7a2e\u6280\u8853\u5e38\u7528\u65bc\u66f4\u8584\u7684\u91d1\u5c6c\u8868\u9762\u934d\u819c\u3001\u77fd\u6676\u5713\u8868\u9762\u5206\u6790\u3001\u73e0\u5bf6\u6216\u85dd\u8853\u54c1\u7684\u6aa2\u67e5\u3002<\/p>\n \u6f2b\u53cd\u5c04\u5f0f\u7684FTIR\u5149\u8b5c\u53c8\u88ab\u7a31\u70baDRIFTS (Diffuse reflectance infrared Fourier transform spectroscopy)\uff0c\u662f\u4e00\u7a2e\u7279\u6b8a\u7684\u53cd\u5c04\u63a1\u6a23\u6280\u8853\uff0c\u6a23\u54c1\u88fd\u5099\u96e3\u5ea6\u8f03\u9ad8\uff0c\u56e0\u6b64\u57f7\u884c\u8d77\u4f86\u8f03\u70ba\u56f0\u96e3\uff0c\u4f46\u5728\u5206\u6790\u571f\u58e4\u3001\u6df7\u51dd\u571f\u6216\u50ac\u5316\u5291\u7b49\u56fa\u9ad4\u6a23\u54c1\u6642\uff0c\u53ef\u4ee5\u7522\u51fa\u51fa\u8272\u7684\u5b9a\u91cf\u7d50\u679c\u3002<\/p>\n<\/div>\u4e00\u3001\u7a7f\u900f\u5f0fFTIR<\/h3>\n
\u57161\uff1a\u7a7f\u900f\u5f0fFTIR<\/h6><\/h6><\/div>
<\/h3>\n
\n
\n
\n
\u4e8c\u3001ATR FTIR<\/h3>\n
\u57162\uff1aATR FTIR<\/h6><\/h6><\/div>
\u57163\uff1aATR FTIR\u7684\u8870\u6e1b\u539f\u7406<\/h6><\/h6><\/div>
ATR\u6676\u9ad4\u6750\u6599\u9078\u64c7\u65b9\u5f0f<\/h4>\n
\u57164\uff1aATR\u6676\u9ad4\u6750\u6599\u7279\u6027\u6bd4\u8f03<\/h6><\/h6><\/div>
\n
\n
\n
\u5176\u4ed6ATR\u6676\u9ad4\u914d\u4ef6<\/h4>\n
\u57165\uff1aATR\u591a\u91cd\u53cd\u5c04\u914d\u4ef6<\/h6><\/h6><\/div>
\u4e09\u3001\u53cd\u5c04\u5f0fFTIR<\/h3>\n
\u57166\uff1a\u53cd\u5c04\u5f0fFTIR<\/h6><\/h6><\/div>
\u57167\uff1a\u53cd\u5c04\u5f0fFTIR\u5206\u70ba\u4e09\u7a2e\u985e\u578b<\/h6><\/h6><\/div>
\u53cd\u5c04-\u5438\u6536\u5f0f(reflection-absorption)\uff1a<\/h4>\n
\u93e1\u9762\u53cd\u5c04\u5f0f(specular reflection)\uff1a<\/h4>\n
\u6f2b\u53cd\u5c04\u5f0f(diffusion reflection)\uff1a<\/h4>\n